rac-2-[(2-Chlorophenyl)(4-chlorophenyl)methyl]-1,3-dioxolane
نویسندگان
چکیده
منابع مشابه
rac-2-[(2-Chlorophenyl)(4-chlorophenyl)methyl]-1,3-dioxolane
The title compound, C(16)H(14)Cl(2)O(2), is a chiral mitotane derivative that contains a dioxolane ring and crystallizes from methanol as a racemic mixture. It was obtained in high yield from mitotane and ethyl-eneglycol in alkaline medium, followed by neutralization with sulfuric acid and extraction with ethyl acetate. The mol-ecular structure is stabilized by an intra-molecular C- H⋯ O hydrog...
متن کاملTricarbonyl(2-methyl-2-η6-phenyl-1,3-dioxolane)chromium(0)
The structure of the title compound, [Cr(C(10)H(12)O(2))(CO)(3)], is presented. The distorted piano-stool geometry features an off-center Cr(CO)(3) fragment which reduces contact with the dioxolane ring. The dioxolane ring, in twisted conformation, is syn-oriented towards the Cr(CO)(3) moiety.
متن کاملSpiro[1,3-dioxolane-2,3′-indolin]-2′-one
The title compound, C(10)H(9)NO(3), was synthesized by the condensation reaction of isatin (systematic name 1H-indole-2,3-dione) with glycol in presence of p-toluene-sulfonic acid. The indol-2-one ring system is essentially planar [N-C-C-C torsion angle = 3.1 (2)°], and the 1,3-dioxolane ring is slightly distorted. The crystal structure exhibits inter-molecular N-H⋯O hydrogen bonds.
متن کامل(4S,5S)-2-(2-Bromophenyl)-1,3-dioxolane-4,5-dicarboxamide
The asymmetric unit of the title compound, C(11)H(11)BrN(2)O(4), contains two crystallographically independent mol-ecules in which the bromo-phenyl rings are oriented at dihedral angles of 39.28 (3)°. The dioxolane rings adopt envelope conformations. Intra-molecular N-H⋯O hydrogen bonds result in the formation of four five-membered rings, having planar and envelope conformations. In the crystal...
متن کامل(4S,5S)-2-(2-Fluorophenyl)-1,3-dioxolane-4,5-dicarboxamide
In the mol-ecule of the title compound, C(11)H(11)FN(2)O(4), the five-membered ring adopts an envelope conformation. An intra-molecular N-H⋯F hydrogen bond occurs. In the crystal structure, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2012
ISSN: 1600-5368
DOI: 10.1107/s1600536812023781